Vanadium

Written by J.A Dobado | Last Updated on April 22, 2024

Vanadium element periodic table

Vanadium is a chemical element with the symbol V and atomic number 23. Vanadium is very hard, strong, and is easy to shape without breaking (ductile and malleable). This metal was first purified in 1869 by chemist Henry Roscoe. Today, it is commonly mined from its ore vanadinite. It is also found in small amounts in carnotite, and patronite, and extracted from these minerals through a process called electrolysis.

Ancient metalworkers used small amounts of vanadium compounds to make a very strong substance called Damascus steel. This is named after the capital of Syria, where smiths made the sharpest swords in the world. Vanadium is still used to harden tools.

Vanadium has many important uses, including in the production of vanadium steel, which is highly resistant to corrosion and is used in the construction of bridges and other structures, and in the production of vanadium pentoxide, which is used as a catalyst in the production of sulfuric acid.

Electron configuration

The electron configuration of an element describes the arrangement of electrons in the atoms of that element, and be used to predict its chemical properties and reactivity.

In the electron configuration notation, the letters "s", "p", "d", and "f" represent the different types of atomic orbitals, and the superscripts indicate the number of electrons in each orbital. The orbitals are filled in a specific order, starting with the lowest energy orbital and working up.

electron configuration of element V

Emission spectra

Each element in the periodic table presents its own unique emission spectra, which is determined by the energy levels of its electrons. When an electron in an atom is excited to a higher energy level, it can de-excite by emitting a photon of light with an energy equal to the difference between the two levels. This results in a characteristic emission line in the spectra (which corresponds to specific wavelengths of light). These spectra are usefull to identify the elements present in a sample.

emmision spectra of element V

Symmary of properties (V)

Atomic weight50.9415(1)
Discoverer (year)Del Rio, Andrés Manuel & Sefström, Nils Gabriel (1830)
Natural formmetallic solid (cubic centred)
Electron configuration[Ar] 3d3 4s2
M.p. (ºC)1890
B.p. (ºC)3380
Earth's crust abundance (ppm)120
Isotope (abundance %)50V (0.250), 51V (99.750)
Density (g/cm3)6.11
vdW radius (pm)207
Covalent radius (pm)144
Electronegativity (Pauling)1.66
Vaporisation enthalpy (Kj/mol)458.60
Fusion enthalpy (kJ/mol)21.50
Specific heat capacity (J/g·K) at 25ºC and 1 at0.49
Thermal conductivity (W/cm·K) at 25 ºC and 1 at0.310
Oxidation number+5, +4, +3, +2
Electronic affinity (eV)0.53
1st Ionization energy (eV)6.7462

Definition of terms in the previous table

  • Atomic weight: The average mass of an element's atoms, typically given in atomic mass units (amu).
  • Natural form: The most stable and abundant form of an element that occurs naturally in the environment.
  • Electron configuration: The arrangement of electrons in an atom or molecule.
  • Melting point: The temperature at which a solid substance turns into a liquid.
  • Boiling point: The temperature at which a liquid substance turns into a gas.
  • Earth's crust abundance (ppm): The concentration of an element in the Earth's crust, typically given in parts per million (ppm).
  • Isotope (abundance %): A variant of an element that has the same number of protons in the nucleus, but a different number of neutrons. The abundance of an isotope is the percentage of the isotope in a sample of the element.
  • Density (g/cm3): The mass of a substance per unit volume.
  • vdW radius (pm): The radius of an atom or molecule as predicted by the van der Waals model, typically given in picometers (pm).
  • Covalent radius (pm): The distance from the center of an atom to the center of another atom with which it is bonded covalently, typically given in picometers (pm).
  • Electronegativity (Pauling): A measure of an atom's ability to attract electrons in a chemical bond, based on the Pauling scale.
  • Vaporisation enthalpy (kJ/mol): The amount of energy required to convert a substance from a liquid to a gas at a constant temperature.
  • Fusion enthalpy (kJ/mol): The amount of energy required to convert a substance from a solid to a liquid at a constant temperature.
  • Specific heat capacity (J/g·K) at 25ºC and 1 at: The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius at a constant pressure.
  • Thermal conductivity (W/cm·K) at 25 ºC and 1 at: The ability of a substance to conduct heat, typically given in watts per centimeter per kelvin.
  • Oxidation number: A positive or negative integer that represents the number of electrons that an atom has gained or lost in a chemical compound.
  • Electronic affinity: The energy change associated with adding an electron to a neutral atom to form a negative ion.
  • 1st Ionization energy: The energy required to remove the most loosely bound electron from a neutral atom.
 

Back to the Periodic Table of the Elements.

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