Welcome to the Organic Chemistry category, where the intricacies of carbon-based molecules are unveiled. Dive into the diverse world of organic compounds, exploring their structures, properties, and reactions. Discover the fascinating realm of functional groups, stereochemistry, and organic synthesis. Uncover the applications of organic chemistry in drug development, materials science, and more. Immerse yourself in the captivating world of organic chemistry and unravel the secrets of carbon-based life.
Go to the page with the solutions to the problems. Aromatic Substitution Reactions in Benzene and Derivatives – list of problems Problem 1) Indicate which of the following structures will be aromatic and which will not: Problem 2) Prepare from benzene the following alkylenes in as few steps as possible. Problem 3) Prepare the following bicyclic … Read more
Go to the page with the list of problems. Alcohols, Ethers and Oxiranes – solutions to the problems Solution 1: The following alcohols will be primary: secondary alcohols are bonded to a -CH- as indicated: and only compound III is a tertiary alcohol. Note that compound VI is a diol (it has two hydroxyls) and … Read more
Go to the page with the solutions to the problems. Alcohols, Ethers and Oxiranes – problem list Problem 1) Classify the following alcohols into primary, secondary and tertiary alcohols. 6.2) Indicate which reagents (a-f) give with propanol and tert-butanol the corresponding alkoxide. a) NH3; b) Nao; c) NaOH; d) NaSO4; e) NaNH2; f) NaH Problem … Read more
Go to the page with the list of problems. Haloalkanes – Alkyl halides – solutions to the problems Solution 1: (a) is a tertiary bromide, (b) is a secondary chloride, (c) is a secondary and allylic bromide, (d) is a primary and allylic chloride, (e) is a primary bromide, (f) is a secondary and benzyl … Read more
Go to the page with the solutions to the problems. Haloalkanes – Alkyl Halides – problem list Problem 1: Classify the type of halide (primary, secondary, tertiary, allylic or benzyl) from the following list and draw the carbocation(s) obtained from each. Problem 2: Classify the type of halide (primary, secondary, tertiary, allylic or benzyl) from … Read more
What is Ciamician-Dennstedt rearrangement? The Ciamician-Dennstedt rearrangement is a chemical reaction that involves the transformation of a pyrrole ring (a five-membered ring) into a six-membered ring by heating it in an alkaline solution with chloroform, CHCl3, or other halogeno compounds. During the reaction, an intermediate product called dichlorocarbene CH2Cl2 is formed, which then reacts with the … Read more
What is Suárez reaction? The Suárez reaction, also known as Suárez fragmentation or Suárez cleavage, involves the photoinduced conversion of hydroxyl-containing substrates with hypervalent iodine I(III) I2, resulting in the formation of the corresponding oxygen-centered radical (see list of acronyms). References J.I. Concepción; C.G. Francisco; R. Hernández; J.A. Salazar; E. Suárez, “Intramolecular hydrogen abstraction. Iodosobenzene … Read more
What is Houben-Hoesch reaction? This reaction was first reported by Hoesch in 1915 and was extended subsequently by Houben in 1926. The Houben-Hoesch reaction is also referred to as the Hoesch synthesis, Houben-Hoesch condensation, Houben-Hoesch acylation, Houben-Hoesch synthesis, or Hoesch reaction. Moreover, the intramolecular version of such reaction is also known as the Houben-Hoesch cyclization. This Houben-Hoesch reaction involves … Read more
What is Haworth phenanthrene synthesis? The Haworth phenanthrene synthesis is a multi-step process used to prepare phenanthrenes from naphthalenes. The process involves several key steps, including Friedel-Crafts acylation, as well as two Clemmensen reductions or Wolff-Kishner reductions. These reactions work together to transform naphthalene into phenanthrene, which can then be utilized in a variety of industrial … Read more
What is Blanc rule? The Blanc rule was originally investigated by Lapworth in 1899 and later by Perkin in 1904 before being generalized by Blanc in 1907. Blanc reported that upon treatment with acetic anhydride, glutaric acid forms an intramolecular anhydride. Similarly, adipic and pimelic acids produce cyclopentanone and cyclohexanone respectively upon undergoing the same … Read more
